Creation of light-emitting structures based on CdSe nanoplatelets

Содержание

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Introduction Light-emitting structures based on CdSe nanoplatelets International Students and Scholars

Introduction

Light-emitting structures based on CdSe nanoplatelets

International Students and Scholars Rock

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Advantages of

CdSe nanoparticles:
1) Narrow photoluminescence band
2) Short photoluminescence lifetime
3) Low Auger recombination rate
Disadvantages of CdSe nanoparticles :
1) High photochemical degradation rate
2) Large number of nonradiative energy relaxation channels

Articles, underlying proposed approach:

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International Students and Scholars Rock Purpose of research 3k Development and

International Students and Scholars Rock

Purpose of research

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Development and experimental investigation of

resonant nanostructures based on CdSe nanoplatelets for low-threshold laser generation
(full research cycle including numerical modelling, fabrication and post-processing of CdSe NPL films, and measurement of emission characteristics)
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International Students and Scholars Rock PLAN for 2021-2025 4k Refinement of

International Students and Scholars Rock

PLAN for 2021-2025

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Refinement of solution-based fabrication methods

for creation of CdSe NPL films
Spin coating
Self-assembly
Development of designs of optical resonators (metasurfaces) for CdSe photoluminescence enhancement and lasing
Fourier modal method calculations
Full wave numerical modelling
Fabrication of optical resonators from CdSe films
Laser ablation / force lithography / focused ion beam milling / …
Experimental studies of the fabricated structures
Photoluminescence -> Amplified spontaneous emission -> Lasing with optical pump
Exploring the possibility of electrically pumped lasing in CdSe nanostructures
Designing the carrier injection layers -> numerical modelling -> fabrication -> testing -> repeat
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Results: Work plan 5k

Results: Work plan

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International Students and Scholars Rock 1) Calculation of TiO2 layer thickness Estimated layer thicknesses: 6k

International Students and Scholars Rock

1) Calculation of TiO2 layer thickness

Estimated layer

thicknesses:

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International Students and Scholars Rock 2) Synthesis of ini CdSe NPL

International Students and Scholars Rock

2) Synthesis of ini CdSe NPL solutions

Two

groups of solutions were prepared:
1) Centrifugation of the ini solution, and then redissolution of the precipitate in hexane
2) Centrifugation of the supernatant and then redissolution in hexane or toluene

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International Students and Scholars Rock Progress 3) Spin-coating on Silicon substrate

International Students and Scholars Rock

Progress

3) Spin-coating on Silicon substrate

7) Applying TiO2
layer

to substrate

5) Self-Assembling on Quartz substrate

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9)

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International Students and Scholars Rock 4) AFM measurements: UNAM From Hexane: 9k

International Students and Scholars Rock

4) AFM measurements:

UNAM

From Hexane:

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International Students and Scholars Rock UNAM From Toluene: 10k 4) AFM measurements:

International Students and Scholars Rock

UNAM

From Toluene:

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4) AFM measurements:

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International Students and Scholars Rock 6) Ellipsometry of CdSe layer on Silicon substrate 11k

International Students and Scholars Rock

6) Ellipsometry of CdSe layer on Silicon

substrate

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International Students and Scholars Rock 5) Applying TiO2 layer to substrates

International Students and Scholars Rock

5) Applying TiO2 layer to substrates

UNAM

ALD goes

wrong:

1.

2.

3.

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EDX

23 nm

27 nm

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International Students and Scholars Rock 6) Ellipsometry of TiO2 layer on Silcon substrate 1. 3. 13k

International Students and Scholars Rock

6) Ellipsometry of TiO2 layer on Silcon

substrate

1.

3.

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International Students and Scholars Rock 7-8) Self-Assembling on Quartz substrate UNAM From Hexane AFM measurements: 14k

International Students and Scholars Rock

7-8) Self-Assembling on Quartz substrate

UNAM

From Hexane

AFM measurements:

14k

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Today… 9) CdSe NPL films on modified substrate Self-Assembling: Spin-coating: 15k

Today…

9) CdSe NPL films on modified substrate

Self-Assembling:

Spin-coating:

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