Chemical bonds

Содержание

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Atom – the smallest unit of matter “indivisible” Helium atom

Atom – the smallest unit of matter “indivisible”

Helium
atom

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electron shells Atomic number = number of Electrons Electrons vary in

electron shells

Atomic number = number of Electrons
Electrons vary in the amount

of energy they possess, and they occur at certain energy levels or electron shells.
Electron shells determine how an atom behaves when it encounters other atoms
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Electrons are placed in shells according to rules: The 1st shell

Electrons are placed in shells according to rules:

The 1st shell can

hold up to two electrons, and each shell thereafter can hold up to 8 electrons.
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Octet Rule = atoms tend to gain, lose or share electrons

Octet Rule = atoms tend to gain, lose or share electrons

so as to have 8 electrons

C would like to
N would like to
O would like to

Gain 4 electrons

Gain 3 electrons

Gain 2 electrons

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Why are electrons important? Elements have different electron configurations different electron

Why are electrons important?

Elements have different electron configurations
different electron configurations mean

different levels of bonding
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Electron Dot Structures Symbols of atoms with dots to represent the

Electron Dot Structures

Symbols of atoms with dots to represent the valence-shell

electrons
1 2 13 14 15 16 17 18
H∙ He:
∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙
Li∙ Be∙ ∙ B ∙ ∙ C ∙ ∙ N ∙ ∙ O ∙ : F ∙ :Ne :
∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙
∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙
Na∙ Mg∙ ∙ Al∙ ∙ Si ∙ ∙P∙ ∙S∙ :Cl ∙ :Ar :
∙ ∙ ∙ ∙ ∙ ∙ ∙ ∙
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Chemical bonds: an attempt to fill electron shells Ionic bonds – Covalent bonds – Metallic bonds

Chemical bonds: an attempt to fill electron shells
Ionic bonds –
Covalent

bonds –
Metallic bonds
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Learning Check ● A. X would be the electron dot formula

Learning Check


A. X would be the electron dot formula

for
1) Na 2) K 3) Al
● ●
B. ● X ● would be the electron dot formula

1) B 2) N 3) P
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IONIC BOND bond formed between two ions by the transfer of electrons

IONIC BOND bond formed between two ions by the transfer of electrons

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Formation of Ions from Metals Ionic compounds result when metals react

Formation of Ions from Metals

Ionic compounds result when metals react with

nonmetals
Metals lose electrons to match the number of valence electrons of their nearest noble gas
Positive ions form when the number of electrons are less than the number of protons
Group 1 metals ⎯→ ion 1+
Group 2 metals ⎯→ ion 2+
Group 13 metals ⎯→ ion 3+
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Formation of Sodium Ion Sodium atom Sodium ion Na ∙ –

Formation of Sodium Ion

Sodium atom Sodium ion
Na ∙

– e− ⎯⎯→ Na +
2-8-1 2-8 ( = Ne)
11 p+ 11 p+
11 e- 10 e-
0 1+
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Formation of Magnesium Ion Magnesium atom Magnesium ion ∙ Mg ∙

Formation of Magnesium Ion

Magnesium atom Magnesium ion

Mg ∙ –

2e− ⎯→ Mg2+
2-8-2 2-8 (=Ne)
12 p+ 12 p+
12 e- 10 e-
0 2+
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Some Typical Ions with Positive Charges (Cations) Group 1 Group 2

Some Typical Ions with Positive Charges (Cations)

Group 1 Group 2 Group 13
H+ Mg2+ Al3+
Li+ Ca2+
Na+ Sr2+
K+ Ba2+

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Learning Check A. Number of valence electrons in aluminum 1) 1

Learning Check

A. Number of valence electrons in aluminum
1) 1 e-

2) 2 e- 3) 3 e-
B. Change in electrons for octet
1) lose 3e- 2) gain 3 e- 3) gain 5 e-
C. Ionic charge of aluminum
1) 3- 2) 5- 3) 3+
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Solution A. Number of valence electrons in aluminum 3) 3 e-

Solution

A. Number of valence electrons in aluminum
3) 3 e-
B. Change

in electrons for octet
1) lose 3e-
C. Ionic charge of aluminum
3) 3+
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Learning Check Give the ionic charge for each of the following:

Learning Check

Give the ionic charge for each of the following:
A. 12

p+ and 10 e-
1) 0 2) 2+ 3) 2-
B. 50p+ and 46 e-
1) 2+ 2) 4+ 3) 4-
C. 15 p+ and 18e-
2) 3+ 2) 3- 3) 5-
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Ions from Nonmetal Ions In ionic compounds, nonmetals in 15, 16,

Ions from Nonmetal Ions

In ionic compounds, nonmetals in 15, 16, and

17 gain electrons from metals
Nonmetal add electrons to achieve the octet arrangement
Nonmetal ionic charge:
3-, 2-, or 1-
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Fluoride Ion unpaired electron octet ∙ ∙ ∙ ∙ 1 -

Fluoride Ion

unpaired electron octet
∙ ∙ ∙ ∙ 1 -
: F

∙ + e− : F :
∙ ∙ ∙ ∙
2-7 2-8 (= Ne)
9 p+ 9 p+
9 e- 10 e-
0 1 -
ionic charge
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Ionic Bond Between atoms of metals and nonmetals with very different

Ionic Bond

Between atoms of metals and nonmetals with very different electronegativity
Bond

formed by transfer of electrons
Produce charged ions all states. Conductors and have high melting point.
Examples; NaCl, CaCl2, K2O
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Ionic Bonds: One Big Greedy Thief Dog!

Ionic Bonds: One Big Greedy Thief Dog!

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1). Ionic bond – electron from Na is transferred to Cl,

1). Ionic bond – electron from Na is transferred to Cl,

this causes a charge imbalance in each atom. The Na becomes (Na+) and the Cl becomes (Cl-), charged particles or ions.
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COVALENT BOND bond formed by the sharing of electrons

COVALENT BOND bond formed by the sharing of electrons

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Covalent Bond Between nonmetallic elements of similar electronegativity. Formed by sharing

Covalent Bond

Between nonmetallic elements of similar electronegativity.
Formed by sharing electron pairs
Stable

non-ionizing particles, they are not conductors at any state
Examples; O2, CO2, C2H6, H2O, SiC
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Covalent Bonds

Covalent Bonds

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Bonds in all the polyatomic ions and diatomics are all covalent bonds

Bonds in all the polyatomic ions and diatomics are all covalent

bonds
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when electrons are shared equally NONPOLAR COVALENT BONDS H2 or Cl2

when electrons are shared equally

NONPOLAR COVALENT BONDS

H2 or Cl2

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2. Covalent bonds- Two atoms share one or more pairs of

2. Covalent bonds- Two atoms share one or more pairs of

outer-shell electrons.

Oxygen Atom

Oxygen Atom

Oxygen Molecule (O2)


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when electrons are shared but shared unequally POLAR COVALENT BONDS H2O

when electrons are shared but shared unequally

POLAR COVALENT BONDS

H2O

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Polar Covalent Bonds: Unevenly matched, but willing to share.

Polar Covalent Bonds: Unevenly matched, but willing to share.

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- water is a polar molecule because oxygen is more electronegative

- water is a polar molecule because oxygen is more electronegative

than hydrogen, and therefore electrons are pulled closer to oxygen.
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METALLIC BOND bond found in metals; holds metal atoms together very strongly

METALLIC BOND bond found in metals; holds metal atoms together very strongly

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Metallic Bond Formed between atoms of metallic elements Electron cloud around

Metallic Bond

Formed between atoms of metallic elements
Electron cloud around atoms
Good

conductors at all states, lustrous, very high melting points
Examples; Na, Fe, Al, Au, Co
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Metallic Bonds: Mellow dogs with plenty of bones to go around.

Metallic Bonds: Mellow dogs with plenty of bones to go around.

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Ionic Bond, A Sea of Electrons

Ionic Bond, A Sea of Electrons

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Metals Form Alloys Metals do not combine with metals. They form

Metals Form Alloys

Metals do not combine with metals. They form
Alloys

which is a solution of a metal in a metal.
Examples are steel, brass, bronze and pewter.
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Formula Weights Formula weight is the sum of the atomic masses.

Formula Weights

Formula weight is the sum of the atomic masses.
Example- CO2
Mass,

C + O + O
12.011 + 15.994 + 15.994
43.999
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Practice Compute the mass of the following compounds round to nearest

Practice

Compute the mass of the following compounds round to nearest tenth

& state type of bond:
NaCl;
23 + 35 = 58; Ionic Bond
C2H6;
24 + 6 = 30; Covalent Bond
Na(CO3)2;
23 + 2(12 + 3x16) = 123; Ionic & Covalent
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