Chemical bonding and Molecular Structure

Содержание

Слайд 2

Topics Covered Ionic Bonds and Compounds Covalent Bonds Lewis Structures Types

Topics Covered

Ionic Bonds and Compounds
Covalent Bonds
Lewis Structures
Types of Covalent

Bonding
Geometry and Polarity of Covalent Molecules
Orbital Hybridization
Sigma and Pi Bonds
Слайд 3

Chemical bond The atoms in molecules held together by strong attractive

Chemical bond

The atoms in molecules held together by strong attractive forces

called chemical bonds
Formed by interaction of valence electrons of the combining atoms
In the formation chemical bonds atoms bond according to the octet rule
Слайд 4

Ionic bond Two atoms with large difference in electronegativity reactivity, there

Ionic bond

Two atoms with large difference in electronegativity reactivity, there is

complete electron transfer
High electronegativity == anion
Low electronegativity == cation
Слайд 5

Ionic bond These two ions are held together by electrostatic forces

Ionic bond

These two ions are held together by electrostatic forces
This

force of attraction between the charged ions is called an ionic bond
Слайд 6

Nomenclature 1. 2. 3.

Nomenclature

1.
2.
3.

Слайд 7

Nomenclature 4. 5.

Nomenclature

4.
5.

Слайд 8

Nomenclature 6.

Nomenclature

6.

Слайд 9

Ionic bond High melting and boiling point – strong electrostatic force

Ionic bond

High melting and boiling point – strong electrostatic force
Conduct

electricity in liquid and aqueous states
Слайд 10

Covalent Bonds Forms when two elements have similar electronegativities They achieve

Covalent Bonds

Forms when two elements have similar electronegativities
They achieve a noble

gas electron configuration by sharing electrons in what is known as a covalent bond
Sometimes need more than one electron to form octet
Слайд 11

Covalent bond Bonds length is the average distance between the two

Covalent bond

Bonds length is the average distance between the two nuclei

of the atoms involved
Bond energy is the energy required to separate two bonded atoms
Слайд 12

Bonds Primary bonding – covalent and ionic Secondary – hydrogen and Van der Vaals

Bonds

Primary bonding – covalent and ionic
Secondary – hydrogen and Van

der Vaals
Слайд 13

Lewis Structures Valence electrons of a covalent bond – bonding electrons

Lewis Structures

Valence electrons of a covalent bond – bonding electrons
Valence electrons

not involved in the covalent bond – lone electron pairs(nonbonding)
Lewis structure – convenient representation of bonding and nonbonding electrons in a molecule
Слайд 14

Lewis Structures More than one Lewis structure for a molecule – resonance

Lewis Structures

More than one Lewis structure for a molecule –

resonance
Слайд 15

Formal Charge

Formal Charge

Слайд 16

Formal Charge

Formal Charge

Слайд 17

Resonance structures

Resonance structures

Слайд 18

Types of covalent bonds Polar covalent bonds – occurs between atoms

Types of covalent bonds

Polar covalent bonds – occurs between atoms with

small difference in electronegativity
Nonpolar covalent bond occurs between atoms that have the same electronegativites
Coordinate Covalent Bond – the shared electron pair comes from the lone pair of one of the atoms in the molecules
Слайд 19

Lewis acid and base Lewis base NH3 – donor of pair

Lewis acid and base

Lewis base NH3 – donor of pair if

electrons
Lewis acid BF3 – acceptor of pair of electrons
Слайд 20

Geometry and polarity The Valence Shell Electron - Pair Repulsion Theory

Geometry and polarity

The Valence Shell Electron - Pair Repulsion Theory

Слайд 21

Geometry and Polarity

Geometry and Polarity

Слайд 22

Hybridization sp – hybridization

Hybridization

sp – hybridization

Слайд 23

Hybridization

Hybridization

Слайд 24

Sigma and Pi bonds

Sigma and Pi bonds

Слайд 25

Metallic bond

Metallic bond

Слайд 26

Summary

Summary

Слайд 27

Summary

Summary

Слайд 28

Summary

Summary